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The book is self-contained and structured to provide straightforward guidance to readers looking to capture fundamentals and gain theoretical and practical knowledge about wireless communications, free-space optical communications, and fiber-optics communications, all whichcan be readily applied in studies, research, and practical applications. The textbook is intended for an upper undergraduate or graduate level courses in fiber-optics communication, wireless communication, and free-space optical communication problems, an appendix with all background material needed, and homework problems. In the second edition, in addition to the existing chapters being updated and problems being inserted, one new chapter has been added, related to the physical-layer security thus covering both security and reliability issues. 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Because most conventional cryptography systems rely on computational security, which guarantees the security against an efficient eavesdropper for a limited time, with the advancement in quantum computing this security can be compromised. To solve these problems, various schemes providing perfect\/unconditional security have been proposed including physical-layer security (PLS), quantum key distribution (QKD), and post-quantum cryptography. Unfortunately, it is still not clear how to integrate those different proposals with higher level cryptography schemes. So the purpose of the Special Issue entitled Physical-Layer Security, Quantum Key Distribution and Post-quantum Cryptography was to integrate these various approaches and enable the next generation of cryptography systems whose security cannot be broken by quantum computers. 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