{"title":"Physics And Chemistry Of Materials With Low-Dimensional Structures","description":null,"products":[{"product_id":"photoelectrochemistry-and-photovoltaics-of-layered-semiconductors-book-a-aruchamy-9780792315568","title":"Photoelectrochemistry and Photovoltaics of Layered Semiconductors","description":"This volume aims at bringing together the results of extensive research done during the last fifteen years on the interfacial photoelectronic properties of the inorganic layered semiconducting materials, mainly in relation to solar energy conversion. Significant contributions have been made both on the fundamental aspects of interface characteristics and on the suitability of the layered materials in photoelectrochemical (semiconductor\/electrolyte junctions) and in solid state photovoltaic(Schottky and p-n junctions) cells. New insights into the physical and chemical characteristics of the contact surfaces have been gained and many new applications of these materials have been revealed. In particular, the basal plane surface of the layered materials shows low chemical reactivity and specific electronic behaviour with respect to isotropic solids. In electrochemical systems, the inert nature of these surfaces characterized by saturated chemical bonds has been recognized from studies on charge transfer reactions and catalysis. In addition, studies on the role of the d-band electronic transitions and the dynamics of the photogene rated charge carriers in the relative stability of the photoelectrodes of the transition metal dichalcogenides have deepened the understanding of the interfacial photoreactions. Transition metal layered compounds are also recognized as ideal model compounds for the studies Involving surfaces: photoreactions, adsorption phenomena and catalysis, scanning tunneling microscopy and spectroscopy and epitaxial growth of thin films. 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Other papers concern the interacting state of electrons with light (polaritons) and the effect of the coupling of electrons with lattice vibrations, with emphasis on the thermal behaviour of the electron levels and on such experimental procedures as piezospectroscopy. Electron-lattice interaction in external magnetic field and transport-related properties due to high light excitation are also con- sidered. The impact of synchroton radiation on condensed matter spectroscopy is dis- cussed in a topical contribution, and optical measurements are presented for extended and impurity levels.","brand":"WoB","offers":[{"title":"GB \/ NEW \/ INGRAM","offer_id":52121760596241,"sku":"NLS9780792303374","price":0.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0784\/4072\/6801\/files\/9780792303374.jpg?v=1757434499"},{"product_id":"low-dimensional-electronic-properties-of-molybdenum-bronzes-and-oxides-book-c-schlenker-9789401066853","title":"Low-Dimensional Electronic Properties of Molybdenum Bronzes and Oxides","description":"The history of low dimensional conductors goes back to the prediction, more than forty years ago, by Peierls, of the instability of a one dimensional metallic chain, leading to what is known now as the charge density wave state. At the same time, Frohlich suggested that an ideal conductivity could be associated to the sliding of this charge density wave. Since then, several classes of compounds, including layered transition metal dichalcogenides, quasi one-dimensional organic conduc- tors and transition metal tri- and tretrachalcogenides have been extensively studied. The molybdenum bronzes or oxides have been discovered or rediscovered as low dimensional conductors in this last decade. A considerable amount of work has now been performed on this subject and it was time to collect some review papers in a single book. Although this book is focused on the molybdenum bronzes and oxides, it has a far more general interest in the field of low dimensional conductors, since several of the molybdenum compounds provide, from our point of view, model systems. This is the case for the quasi one-dimensional blue bronze, especially due to the availability of good quality large single crystals. 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This resulting volume is aimed at researchers with specialist interests in the particular materials discussed but who may also wish to examine the related phenomena observed in different systems, and at a more general solid state audience with broad interests in electronic properties and low dimensional phenomena. 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In the last decade this field has experienced a rapid development and represents now an established specific domain of solid state research and materials science. Substantial progress has been made with respect to an understanding of the complex relationship between structure, bonding, physical properties and chemical reactivity since the first volume on the subject appeared in this series in 1979 (Intercalated Layered Materials, F. Levy, ed.). The purpose of this volume is to present a survey on progress and per­ spectives based on the treatment of a series of major areas of activities in this field. By the very nature of its subject this monograph has an interdisciplinary character and addresses itself to chemists, physicists and materials scien­ tists interested in intercalation research and related aspects such as design and characterization of complex materials, low temperature synthesis, solid state reaction mechanisms, electronic\/ionic conductivity, control of electronic properties of solids with different structural dimensionality and application of intercalation systems. 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The existence of carbyne was first disclosed by Russian researchers in 1960. It was obtained for the first time via oxidative dehydropolycondensation of acetylene based on the Glaser coupling of ethynyl compounds. 1. Introduction The polymeric nature of carbon was first pointed out by Mendeleev. He wrote: The molecules of coal, graphite, and diamond are very complicated, and carbon atoms exhibit the capability of binding one to another to form complex molecules in all compounds of carbon. None of the elements possesses an ability of complicating in such an extent as does carbon. There is still no basis to define the polymerization degree of the coal, graphite, or diamond molecules. One should believe, however that they contain en species, where 'n' is a large value  IJ. Until the 1960s only two allotropic forms of carbon were known, viz., graphite and diamond, including their polymorphous modifications. For a long time 'amorphous carbon' was also included among the simple forms. 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This book brings together for the first time the  crystallographic descriptions and experimental methods for the  structural and microstructural analysis of modulated crystals as  described by well-known researchers in the various areas. The emphasis  is on charge density wave modulations, and the detailed analysis of  the prototypical NbTe4\/TaTe4 system gives practical applications of  the methods. 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These included in particular Nevill (now Sir Nevill) Mott, perhaps the friendliest among many kind and friendly people we met then. Professor Kamimura became associated with Sir Rudolf Peierls in the 1950s, when he translated, with his colleagues, Peierls's 1955 textbook, Quantum Theory of Solids, into Japanese. This edition, to which Sir Rudolf himself contributed a preface, benefitted early generations of Japanese solid state physicists. Later in 1974\/5, during a sabbatical year spent at the Cavendish Laboratory, Professor Kamimura met and began a long association with Sir Nevill Mott. In particular, they developed ideas for disordered systems. One of the outcomes is a paper coauthored by them on ESR-induced variable­ range hopping in doped semiconductors. 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Significant contributions have been made both on the fundamental aspects of interface characteristics and on the suitability of the layered materials in photoelectrochemical (semiconductor\/electrolyte junctions) and in solid state photovoltaic(Schottky and p-n junctions) cells. New insights into the physical and chemical characteristics of the contact surfaces have been gained and many new applications of these materials have been revealed. In particular, the basal plane surface of the layered materials shows low chemical reactivity and specific electronic behaviour with respect to isotropic solids. In electrochemical systems, the inert nature of these surfaces characterized by saturated chemical bonds has been recognized from studies on charge transfer reactions and catalysis. 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It was obtained for the first time via oxidative dehydropolycondensation of acetylene based on the Glaser coupling of ethynyl compounds. 1. Introduction The polymeric nature of carbon was first pointed out by Mendeleev. He wrote: The molecules of coal, graphite, and diamond are very complicated, and carbon atoms exhibit the capability of binding one to another to form complex molecules in all compounds of carbon. None of the elements possesses an ability of complicating in such an extent as does carbon. There is still no basis to define the polymerization degree of the coal, graphite, or diamond molecules. One should believe, however that they contain en species, where 'n' is a large value  IJ. Until the 1960s only two allotropic forms of carbon were known, viz., graphite and diamond, including their polymorphous modifications. For a long time 'amorphous carbon' was also included among the simple forms. 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Relations were established between superconductivity and the fundamental properties of solids, resulting in a possible upper limit of the critical temperature at about 23 K. The breakthrough that revolutionized the field was made in 1986 by Bednorz and Muller with the discovery of high-temperature superconductivity in layered copper-oxide perovskites. Today the record in transition temperature is 133 K for a Hg based cuprate system. The last decade has not only seen a revolution in the size of the critical temperature, but also in the myriads of research groups that entered the field. In addition, high-temperature superconductivity became a real interdisciplinary topic and brought together physicists, chemists and materials scientists who started to investigate the new compounds with almost all the available experimental techniques and theoretical methods. 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