Free Shipping In Australia
Handbook of Grignard Reagents By Gary S. Silverman (Askema, Inc., King of Prussia, Pennsylvania, USA)

Handbook of Grignard Reagents
by Gary S. Silverman (Askema, Inc., King of Prussia, Pennsylvania, USA)

Out of Stock
$209.99
inc. GST
Offers the theoretical and practical information necessary to explore fresh applications for Grignard reagents, presenting a comprehensive overview of research activities in Grignard chemistry. This book surveys specific reactions and applications of Grignard reagents, organized by type of substrate and the general category of reaction.
Only 0 left

Handbook of Grignard Reagents Summary


Handbook of Grignard Reagents by Gary S. Silverman (Askema, Inc., King of Prussia, Pennsylvania, USA)

This handbook provides the theoretical and practical information necessary to explore new applications for Grignard reagents on a day-to-day basis, presenting a comprehensive overview of current research activities in Grignard chemistry. This book surveys specific reactions and applications of Grignard reagents, organized by type of substrate and the general category of reaction. It also summarizes the spectrum of reactions exhibited by Grignard reagents.

Why buy from World of Books

Our excellent value books literally don't cost the earth
Free delivery in Australia
Read more here
Every used book bought is one saved from landfill

Table of Contents


Part 1 Methods of Grignard reagent preparation: common method of Grignard reagent preparation; preparation of Grignard reagents from olefins and acetylenes; magnesium activation. Part 2 Safe handling practices: safe handling practices of industrial scale Grignard reagents. Part 3 Analyses of Grignard reagents: wet analyses of Grignard reagents; infrared and raman spectroscopy; nuclear magnetic resonance analysis of Grignard reagents; crystal structures of Grignard reagents. Part 4 Mechanisms and structure-reactivity relationships: mechanism of Grignard reagent formulation; mechanism of reactions in Grignard reagents; structure-reactivity relationships; the composition of Grignard reagents in solution - the Schlenk equilibrium and its effect on reactivity; effect of tris(pyrazolyl)hydrobotato ligation. Part 5 General reactions of Grignard reagents: nucleophilic substitution with electrophilic organic, main group and transition metal species; nucleophilic addition to unconjugated C-C multiple bond; nucleophilic addition of C-C multiple bonds - O, S, N, P; nucleophilic addition to conjugated carbon-carbon bonds; nucleophilic addition to conjugated carbon-heteroatom multiple bonds - O, S, N; nucleophilic addition to organometallic vinylidene and allyl complexes. Part 6 Special topics - applications and reactions of Grignard reagents: the Barbier reaction; Grignard reagents as bases; Sn2 versus Sn21; dihalide-derived di-Grignard reagents - preparation and reactions; formation and reactions of substituted (2-butene-1,4-diyl)magnesium complexes; spiroannulations using substituted (2-butene-1,4-diyl)magnesium complexes; asymmetric synthesis using Grignard reagents; metal-catalyzed reactions; the preparation of 1,1-bimetallics of magnesium and zinc; alkynyl Grignard reagents and their uses; Grignard reagents and silanes; Ziegler-Natta catalysis; organomagnesium compounds as polymerization initiators.

Additional information

GOR010228246
Handbook of Grignard Reagents by Gary S. Silverman (Askema, Inc., King of Prussia, Pennsylvania, USA)
Gary S. Silverman (Askema, Inc., King of Prussia, Pennsylvania, USA)
Chemical Industries
Used - Very Good
Hardback
Taylor & Francis Inc
1996-04-25
736
0824795458
9780824795450
N/A
Book picture is for illustrative purposes only, actual binding, cover or edition may vary.
This is a used book - there is no escaping the fact it has been read by someone else and it will show signs of wear and previous use. Overall we expect it to be in very good condition, but if you are not entirely satisfied please get in touch with us.