Organic Functional Group Interconversion and Protection ; 1. Best Synthetic Methods: Functional Group Transformations May 17, 2010 ; 2. Functional Group Transformations : The Castle Synthesis of Celogentin C October 25, 2010 ; 3. Organic Functional Group Conversion March 28, 2011 ; 4. Advances in Organic Functional Group Transformation May 16, 2011 ; 5. Organic Functional Group Transformation October 31, 2011 ; 6. Best Synthetic Methods: Reduction February 22, 2010 ; 7. Best Synthetic Methods: Oxidation March 8, 2010 ; 8. Best Synthetic Methods: Oxidation and Reduction May 24, 2010 ; 9. Oxidation and Reduction May 23, 2011 ; 10. Organic Functional Group Protection March 15, 2010 ; 11. Functional Group Protection: The Kraus Synthesis of Bauhinoxepin J September 13, 2010 ; 12. Functional Group Protection November 8, 2010 ; 13. Organic Functional Group Protection September 12, 2011 ; 14. Organic Functional Group Protection and Deprotection November 14, 2011 ; Flow Methods ; 15. Flow Methods for Organic Synthesis October10, 2011 ; C-H Functionalization ; 16. C-H Functionalization: The White Synthesis of 6-Deoxyerythronolide B September 27, 2010 ; 17. C-H Functionalization: The Chen Synthesis of Celogentin C March 21, 2011 ; 18. Functionalization and Homologation of C-H Bonds September 26, 2011 ; Carbon-Carbon Bond Construction ; 19. New Methods for Carbon-Carbon Bond Construction March 22, 2010 ; 20. Best Synthetic Methods: C-C Bond Construction May 31 , 2010 ; 21. New Methods for C-C Bond Construction February 21, 2011 ; 22. New Methods for C-C Bond Construction: The Burke Synthesis of (-)-Peridinin February 28, 2011 ; 23. Carbon-Carbon Bond Formation May 30, 2011 ; Reactions of Alkenes ; 24. Best Synthetic Methods: Reactions of Alkenes March 29, 2010 ; 25. Alkene Reactions: The Dabdoub/Baroni Synthesis of (+-)-Dihydroactinidiolide September 20, 2010 ; 26. Reactions of Alkenes March 14, 2011 ; 27. Functionalization and Homologation of Alkenes September 19, 2011 ; Alkene and Alkyne Metathesis ; 28. Advances in Alkene Metathesis: The Hoveyda Synthesis of (+)-Quebrachamine January 11, 2010 ; 29. Alkene and Alkyne Metathesis: Navenone B (Cossy), (+)-Asperpentyn (Daesung Lee), (-)-Amphidininolide K (Eun Lee), Norhalichondrin B (Phillips) January 18, 2010 ; 30. Progress in Alkene and Alkyne Metathesis: (+)-5-epi-Citreoviral (Funk) and (+-)-Poitediol (Vanderwal) June 28, 2010 ; 31. Alkene and Alkyne Metathesis: Grandisol (Goess), 8-Epihalosilane (Kouklovsky/Vincent), (+)-Chinensiolide B (Hall) January 17, 2011 ; 32. Alkene and Alkyne Metathesis: (+)-Anamarine (Sabitha), (+-)-Pseudotabersonine (Martin), Lactimidomycin (Furstner) June 27, 2011 ; Enantioselective Construction of Acyclic Stereogenic Centers ; 33. nantioselective Preparation of Alcohols and Amines: The Suh Synthesis of (-)-Macrosphelide J January 25, 2010 ; 34. Enantioselective Construction of Alcohols and Amines July 12, 2010 ; 35. Construction of Oxygenated and Aminated Stereogenic Centers January 24, 2011 ; 36. Enantioselective Preparation of Alcohols and Amines: The Lam Synthesis of (+)-Tanikolide July 11, 2011 ; 37. Enantioselective Construction of Alkylated Centers: The Maier Synthesis of Platencin February 8, 2010 ; 38. Enantioselective Construction of Alkylated Stereogenic Centers July 19, 2010 ; 39. Construction of Alkylated Stereogenic Centers January 31, 2011 ; 40. Enantioselective Preparation of Alkylated Stereogenic Centers July 18, 2011 ; 41. Construction of Arrays of Stereogenic Centers: The Zhang Synthesis of (+)-Podophyllotoxin February 15, 2010 ; 42. Enantioselective Construction of Arrays of Stereogenic Centers: The Breit Synthesis of (+)-Bourgeanic Acid July 26, 2010 ; 43. Stereocontrolled Construction of Arrays of Stereogenic Centers: The Mullins Synthesis of (-)-Lasiol February 14, 2011 ; 44. Establishing Arrays of Stereogenic Centers: The Sato/Chida Synthesis of (-)-Kainic Acid July 25, 2011 ; Construction of C-O Rings ; 45. Stereoselective C-O Ring Construction: The Jamison Synthesis of (-)-Gloeosporone April 12, 2010 ; 46. Stereocontrolled Construction of C-O Rings: The Seeberger/Hilvert Synthesis of KDN November 29, 2010 ; 47. C-O Ring Construction: The Theodorakis Synthesis of (-)-Englerin April 11, 2011 ; 48. Synthesis of Naturally-Occurring Cyclic Ethers: Boivivianin B (Murakami), SC-D13-9-IsoF (Taber), Brevisamide (Panek, Lindsley, Ghosh), Gambierol (Mori) April 19, 2010 ; 49. Stereoselective C-O Ring Construction: (+)-Pachastrissamine (Fujii/Ohno), Aspalathin (Minehan), (+)-Varitriol (Ghosh), Aspercyclide A (Spivey), Atnangien (Menche) January 10, 2011 ; 50. C-O Ring Construction: (-)-Sclerophytin A (Morken), (+)-Dictyosphaeric Acid (Taylor), Goniothalesdiol (Xie/She), (-)-7-Deoxyloganin (Lupton), (-)-Apicularen A (Uenishi), L-783, 277 (Banwell) April 18, 2011 ; Construction of C-N Rings ; 51. Stereocontrolled C-N Ring Construction: The Takayama Synthesis of Lycoposerramine-C April 26, 2010 ; 52. Stereocontrolled C-N Ring Construction: The Pyne Synthesis of Hyacinthacine B7 November 15, 2010 ; 53. C-N Ring Construciton: The Zakarian Synthesis of (-)-Rhazinilam April 25, 2011 ; 54. C-N Ring Construction: The Synthesis of Decursivinme by Mascal and by Jia November 21, 2011 ; 55. Alkaloid Synthesis: (S)-Nicotine (Helmchen), (+)-CP-99,994 (Shi), (-)-Adaline (Yu), (-)-Securinine (Bayon/Figueredo), Alkaloid 223A (Aube), (-)-Huperzine A (Fukuyama) May 10, 2010 ; 56. Synthesis of C-N Natural Products: (-)-a-Kainic Acid (Helmchen), (+)-Tylophorine (Opatz), (-)-Lycoprine A (Rychnovsky), Fluvirucidine A2 (Suh), Complanidine A (Sarpong) November 22, 2010 ; 57. Alkaloid Synthesis: (+)-Preussin (Britton), (+-)-Xenovenine (Livinghouse), (+)-Subincanadine F (Li), (+-)-Strychnine (Reissig), (-)-Virginiamycin M2 (Panek) May 9, 2011 ; 58. Alkaloid Synthesis: Mearsine (Taylor), Cephalotaxine (Li), Cocaine (Shing), Quinine (Hatakeyama), Cleavamine (Bennasar), Strychnine (Vanderwal) November 28, 2011 ; Substituted Benzene Derivatives ; 59. Benzene Derivatives: The Tanino-Miyashita Synthesis of Zoanthenol June 14, 2010 ; 60. Substituted Benzenes: The Saikawa/Nakata Synthesis of Kendomycin October 11, 2010 ; 61. Substituted Benzenes: The Kirsch Synthesis of Cybrodol June 13, 2011 ; 62. Substituted Benzenes: The Piers/Lau Synthesis of Hamigeran B October 17, 2011 ; Heteroaromatic Derivatives ; 63. Heteroaromatic Construction: The Jia Synthesis of (-)-cis-Clavicipitic Acid June 21, 2010 ; 64. Heteroaromatics: The Mal Synthesis of Clausevatine D October 18, 2010 ; 65. Heteroaromatic Construction: The Fukuyama Synthesis of Tryprostatin A June 20, 2011 ; 66. Heteroaromatic Construction: The Wipf Synthesis of Cycloclavine October 24, 2011 ; Organocatalyzed C-C Ring Construction ; 67. Organocatalytic Carbocyclic Construction: The Christmann Synthesis of (+)-Rotundial August 16, 2010 ; 68. Enantioselective Organocatalytic C-C Ring Construction December 20, 2010 ; 69. Organocatalysis of C-C Ring Construction: The MacMillan Synthesis of (+)-Frondosin B August 15, 2011 ; 70. Organocatalyzed C-C Ring Construction: The Thomson Synthesis of Streptorububin B December 12, 2011 ; Transition Metal Catalyzed C-C Ring Construction ; 71. Metal-Mediated Carbocyclic Construction: The Kobayashi Synthesis of (+)-Fomitellic Acid B August 9, 2010 ; 72. Transition-Metal Catalyzed Ring Construction: The Yu Synthesis of a-Agorafuran December 13, 2010 ; 73. Metal-Mediated Carbocyclic Construction: The Simpkins Synthesis of Ialibinones A and B August 8, 2011 ; 74. Metal Catalyzed C-C Ring Construction: The Nevado Route to (-)-Frondosin A December 19, 2011 ; Intermolecular and Intramolecular Diels-Alder Reactions ; 75. Tethered Diels-Alder Cycloadddition: (+-)-Neovibsanin B (Imagawa, Nishizawa), Valerenic Acid (Mulzer), (-)-Himandrine (Movassaghi), (+-)-Pallavicinolide (Wong), (+)-Phomopsidin (Nakada) August 30, 2010 ; 76. Intramolecular Diels-Alder Cycloaddition: Brombyin II (Lygo), Ptilocaulin (Livinghouse), Bistellettadine A (Snider), (-)-Pycnanthuquinone C (Trauner), (+)-Caribenol A (Li/Yang) August 29, 2011 ; Stereocontrolled C-C Ring Construction ; 77. Carbocyclic Construction: The Deng Synthesis of (-)-Plicatic Acid August 23, 2010 ; 78. New Methods for Carbocyclic Construction: The Kim Synthesis of Pentalenene December 27, 2010 ; 79. Other Methods for Carbocyclic Construction: The Porco Synthesis of (-)-Hyperibone K August 22, 2011 ; 80. Stereoselective Carbocyclic Construction: The Metz Synthesis of (+-)-Codeine December 26, 2011 ; Classics in Total Synthesis ; 81. The Williams Synthesis of (-)-4-Hydroxydictyolactone January 4, 2010 ; 82. The Nakada Synthesis of (-)-FR182877 February 1, 2010 ; 83. The Trost Synthesis of (-)-Pseuodolaric Acid B March 1, 2010 ; 84. The Corey Synthesis of (+)-Lupeol April 5, 2010 ; 85. The Dixon Synthesis of (-)-Nakadomarin A May 3, 2010 ; 86. The Magnus Synthesis of (+-)-Codeine June 7, 2010 ; 87. The Nicolaou Synthesis of (+)-Hirsutellone B July 5, 2010 ; 88. The Nicolaou Synthesis of (+)-Vannusal August 2, 2011 ; 89. The Baran Synthesis of Vinigrol September 6, 2010 ; 90. The Overman Synthesis of Briarellin B October 4, 2010 ; 91. The Shair Synthesis of Cephalostatin 1 November 1, 2010 ; 92. The Chen Synthesis of (-)-Nakiterpiosin December 6, 2010 ; 93. The Tanino Synthesis of (-)-Glycinoeclepin A January 3, 2011 ; 94. The Boger Synthesis of (-)-Vindoline February 7, 2011 ; 95. The Bradshaw/Bonjoch Synthesis of (-)-Anominine March 7, 2011 ; 96. The Ma Synthesis of (-)-GB 13 April 4, 2011 ; 97. The Trost Synthesis of Bryostatin 16 May 2, 2011 ; 98. The Li/Zhang Synthesis of (+-)-Maoecrystal V June 6, 2011 ; 99. The Funk Synthesis of (-)-Nakadomarin A July 4, 2011 ; 100. The Boger Synthesis of (+)-Complestatin August 1, 2011 ; 101. The Overman Synthesis of (-)-Actinophyllic Acid September 5, 2011 ; 102. The Tanino/Miyashita Synthesis of Solanoeclepin A October 3, 2011 ; 103. The Rawal Synthesis of N-Methylwelwitindolinone D Isonitrile November 7, 2011 ; 104. The Garg Synthesis of (+-)-Aspidophylline A December 5, 2011